The Effect of Active Metals Cu - Fe in Alumina Catalytic Converters on Motor Vehicle Exhaust Emissions
DOI:
https://doi.org/10.70822/evrmata.vi.117Keywords:
Cu–Fe active metals, alumina-based catalytic converter, exhaust emissions, CO emission reduction, HC emission reduction, CO₂ and O₂ levelsAbstract
This study addresses the growing environmental concerns caused by motor vehicle emissions, particularly CO, HC, CO₂, and O₂, which contribute to urban air pollution. The goal is to evaluate the effect of Cu–Fe active metals in alumina-based catalytic converters on exhaust gas emissions from a 110cc gasoline motorcycle. The method involves preparing Cu–Fe/Al₂O₃ catalysts in varying compositions (80%, 70%, and 60% alumina with Cu–Fe) and testing them in a modified exhaust system at different engine RPMs (idle, 3000 RPM, and 6000 RPM). The results show significant reductions in CO and HC emissions across all RPM levels, with the 60% alumina – 40% Cu–Fe composition performing the best, especially at higher RPMs where oxidation reactions are most effective. The increase in CO₂ levels and decrease in O₂ further confirmed the improved oxidation process. Specifically, CO emissions were reduced by 30%, HC by 25%, while CO₂ levels increased by 15%. In conclusion, Cu–Fe/Al₂O₃ catalytic converters provide a cost-effective and efficient alternative to precious metal-based catalysts, with potential applications in reducing vehicle emissions without major cost increases.
References
S. Dey dan N.S. Mehta, “Automobile pollution control using catalysis,” Resources, Environment and Sustainability, vol. 2, Dec. 2020. doi: 10.1016/j.resenv.2020.100006.
D.N. Belton dan K.C. Taylor, “Automobile exhaust emission control by catalysts,” Current Opinion in Solid State & Materials Science, vol. 4, no. 1, pp. 97–102, Feb. 1999. doi: 10.1016/S1359 0286(99)80017 5.
G. Kavitha, “Thermodynamic and Emission Analysis of Waste Plastic Oil ...”, Fuel Processing Technology, 2025. doi: 10.1016/j.fuproc.2025.2642.
A. Ghofur, “Potential fly ash waste as catalytic converter for reduction”, Materials Today: Proceedings, vol. 5, 2018. doi: 10.1016/j.matpr.2018.0147X.
S. Tian et al., “Toluene oxidation over the alumina supported ceria based ...”, Journal of Environmental Chemical Engineering, 2025. doi: 10.1016/j.jece.2025.6350.
S. Gomes et al., “Performance of copper aluminum catalysts impregnated with potassium in NO and N₂O reduction by CO,” Catalysis Today, vol. 447, pp. 115140, Mar. 2025. doi: 10.1016/j.cattod.2024.115140.
L. Castoldi et al., “New insights on the adsorption, thermal decomposition ...”, Applied Catalysis A: General, 2018. doi: 10.1016/j.apcata.2017.9311.
S. Dey, “Low temperature catalytic conversion of carbon monoxide ...”, Journal of Catalysis, 2022. doi: 10.1016/j.jcat.2022.0026. [9] L. Wang et al., “Research advances of rare earth catalysts for catalytic purification of vehicle exhausts,” Journal of Rare Earths, 2021. doi: 10.1016/j.jre.2021.05.001.
R. Mutschler et al., “CO₂ hydrogenation reaction over pristine Fe, Co, Ni, Cu and Al₂O₃ supported Ru ...”, Journal of Catalysis, vol. 362, 2018. doi: 10.1016/j.jcat.2018.08.002.
K. Arve et al., “From a fixed bed Ag–alumina catalyst to a modified reactor ...”, Chemical Engineering Science, 2004. doi: 10.1016/j.ces.2004.06414.
P.L. Silveston et al., “Automotive exhaust catalysis under periodic operation,” Catalysis Today, 1995. doi: 10.1016/0920 5861(95)0107Q.
W. Kim, “Selective recovery of catalyst layer from supporting matrix ...,” Journal of Hazardous Materials, 2010. doi: 10.1016/j.jhazmat.2010.00778.
L.F. de Mello et al., “NO reduction with acetaldehyde on alumina supported Pd”, Journal of Catalysis, 2006. doi: 10.1016/j.jcat.2006.01795.
S. Ozawa et al., “Thermal stabilization of catalytic compositions”, Journal of Alloys and Compounds, 2006. doi: 10.1016/j.jallcom.2005.00673.
A.G. James et al., “A new material for combustion exhaust aftertreatment ...”, Chemical Engineering Journal, 2022. doi: 10.1016/j.cej.2021.3391X.
Research on metal support interactions, “Progress on metal support interactions in Pd based ...”, Catalysis Today, 2023. doi: 10.1016/j.cattod.2022.01009.
A.Satsuma et al., “In situ FT/IR study of selective catalytic reduction of NO”, Catalysis Today, 2003. doi: 10.1016/S0360 1285(02)00033 3.



